Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II).
نویسندگان
چکیده
N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine-alkene ligand for Pd(0) and Pd(II), promoting direct alkyl-alkyl and indirect alkyl-halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine-alkene)Pd(0) complex.
منابع مشابه
Combined DFT and experimental studies of C-C and C-X elimination reactions promoted by a chelating phosphine-alkene ligand: the key role of penta-coordinate Pd(II.).
A combined computational and experimental study of the coordination chemistry of phosphine-alkene ligand L1 (N-diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene) with Pd(0) and Pd(II) is presented. Experimentally it is established that ligand L1 promotes direct alkyl-alkyl and indirect alkyl-halide reductive elimination from Pd(II) species, affording the palladium(0) complex [Pd(κ(2)-P,C-L1...
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 84 شماره
صفحات -
تاریخ انتشار 2012